J. Phys. Soc. Jpn. 79 (2010) 011011 (12 pages) |Previous Article| |Next Article| |Table of Contents|
|Full Text PDF (3984K)| |Buy This Article|
SPECIAL TOPICS
Competing Orders in PZN–xPT and PMN–xPT Relaxor Ferroelectrics
Guangyong Xu
Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973, U.S.A.
(Received July 16, 2009; Accepted August 27, 2009; Published January 12, 2010)
Neutron and x-ray scattering studies on relaxor ferroelectric systems Pb(Zn1/3Nb2/3)O3 (PZN), Pb(Mg1/3Nb2/3)O3 (PMN), and their solid solutions with PbTiO3 (PT) have shown that inhomogeneities and disorder play important roles in the materials properties. Although a long-range polar order can be established at low temperature – sometimes with the help of an external electric field; short-range local structures called the “polar nano-regions” (PNR) still persist. Both the bulk structure and the PNR have been studied in details. The coexistence and competition of long- and short-range polar orders and how they affect the structural and dynamical properties of relaxor materials are discussed.
©2010 The Physical Society of Japan
URL:
http://jpsj.ipap.jp/link?JPSJ/79/011011/
DOI: 10.1143/JPSJ.79.011011
- S.-E. Park and T. R. Shrout:
J. Appl. Phys. 82 (1997) 1804[AIP Scitation].
- K. Uchino: Piezoelectric Actuators and Ultrasonic Motors (Kluwer Academic, Boston, MA, 1996).
- R. F. Service: Science 275 (1997) 1878[Science].
- G. A. Smolenskii, V. Isupov, A. Agranovskaya, and S. N. Popov: Sov. Phys. Solid State 2 (1961) 2584.
- Y. Imry and S. Ma:
Phys. Rev. Lett. 35 (1975) 1399[APS].
- B. I. Halperin and C. M. Varma:
Phys. Rev. B 14 (1976) 4030[APS].
- V. Westphal, W. Kleemann, and M. D. Glinchuk:
Phys. Rev. Lett. 68 (1992) 847[APS].
- R. Fisch:
Phys. Rev. B 67 (2003) 094110[APS].
- R. Pirc and R. Blinc:
Phys. Rev. B 60 (1999) 13470[APS].
- P. Bonneau, P. Garnier, E. Husson, and A. Morell: Mater. Res. Bull. 24 (1989) 201.
- N. de Mathan, E. Husson, G. Calvarin, J. R. Gavarri, A. W. Hewat, and A. Morell:
J. Phys.: Condens. Matter 3 (1991) 8159[IoP STACKS].
- Z.-G. Ye and H. Schmid: Ferroelectrics 145 (1993) 83.
- J. Kuwata, K. Uchino, and S. Nomura: Ferroelectrics 37 (1981) 579.
- A. Lebon, H. Dammak, G. Calvarin, and I. O. Ahmedou:
J. Phys.: Condens. Matter 14 (2002) 7035[IoP STACKS].
- G. Xu, Z. Zhong, Y. Bing, Z.-G. Ye, C. Stock, and G. Shirane:
Phys. Rev. B 67 (2003) 104102[APS].
- G. Xu, Z. Zhong, Y. Bing, Z.-G. Ye, C. Stock, and G. Shirane:
Phys. Rev. B 70 (2004) 064107[APS].
- P. M. Gehring, W. Chen, Z.-G. Ye, and G. Shirane:
J. Phys.: Condens. Matter 16 (2004) 7113[IoP STACKS].
- G. Xu, D. Viehland, J. F. Li, P. M. Gehring, and G. Shirane:
Phys. Rev. B 68 (2003) 212410[APS].
- G. Xu, H. Hiraka, K. Ohwada, and G. Shirane:
Appl. Phys. Lett. 84 (2004) 3975[AIP Scitation].
- K. H. Conlon, H. Luo, D. Viehland, J. F. Li, T. Whan, J. H. Fox, C. Stock, and G. Shirane:
Phys. Rev. B 70 (2004) 172204[APS].
- G. Xu, P. M. Gehring, C. Stock, and K. Conlon: Phase Transitions 79 (2006) 135.
- J. Kuwata, K. Uchino, and S. Nomura: Jpn. J. Appl. Phys. 21 (1982) 1298.
- J.-M. Kiat, Y. Uesu, B. Dkhil, M. Matsuda, C. Malibert, and G. Calvarin:
Phys. Rev. B 65 (2002) 064106[APS].
- A. K. Singh and D. Pandey:
Phys. Rev. B 67 (2003) 064102[APS].
- D. La-Orauttapong, B. Noheda, Z.-G. Ye, P. M. Gehring, J. Toulouse, D. E. Cox, and G. Shirane:
Phys. Rev. B 65 (2002) 144101[APS].
- D. E. Cox, B. Noheda, G. Shirane, Y. Uesu, K. Fujishiro, and Y. Yamada:
Appl. Phys. Lett. 79 (2001) 400[AIP Scitation].
- B. Noheda, D. E. Cox, G. Shirane, J. Gao, and Z.-G. Ye:
Phys. Rev. B 66 (2002) 054104[APS].
- B. Noheda, D. E. Cox, and G. Shirane: Ferroelectrics 267 (2002) 147.
- Z.-G. Ye, B. Noheda, M. Dong, D. Cox, and G. Shirane:
Phys. Rev. B 64 (2001) 184114[APS].
- D. Vanderbolt and M. H. Cohen:
Phys. Rev. B 63 (2001) 094108[APS].
- B. Noheda, D. E. Cox, G. Shirane, S.-E. Park, L. E. Cross, and Z. Zhong:
Phys. Rev. Lett. 86 (2001) 3891[APS].
- H. Fu and R. E. Cohen:
Nature 403 (2000) 281[CrossRef].
- B. Noheda, Z. Zhong, D. E. Cox, G. Shirane, S.-E. Park, and P. Rehrig:
Phys. Rev. B 65 (2002) 224101[APS].
- K. Ohwada, K. Hirota, P. W. Rehrig, Y. Fujii, and G. Shirane:
Phys. Rev. B 67 (2003) 094111[APS].
- F. Bai, N. Wang, J. Li, D. Viehland, P. Gehring, G. Xu, and G. Shirane:
J. Appl. Phys. 96 (2004) 1620[AIP Scitation].
- H. Cao, J. Li, D. Viehland, and G. Xu:
Phys. Rev. B 73 (2006) 184110[APS].
- G. Burns and F. H. Dacol:
Phys. Rev. B 28 (1983) 2527[APS].
- L. E. Cross: Ferroelectrics 76 (1987) 241.
- H. Hiraka, S.-H. Lee, P. M. Gehring, G. Xu, and G. Shirane:
Phys. Rev. B 70 (2004) 184105[APS].
- B. P. Burton, E. Cockayne, and U. V. Waghmare:
Phys. Rev. B 72 (2005) 064113[APS].
- O. Svitelskiy, J. Toulouse, and Z.-G. Ye:
Phys. Rev. B 68 (2003) 104107[APS].
- V. Bovtun, S. Kamba, A. Pashkin, M. Savinov, P. Samoukhina, J. Petzelt, I. P. Bykov, and M. D. Glinchuk: Ferroelectrics 298 (2004) 23.
- P. Lehnen, W. Kleemann, T. Woike, and R. Pankrath:
Phys. Rev. B 64 (2001) 224109[APS].
- V. V. Shvartsman and A. L. Kholkin:
Phys. Rev. B 69 (2004) 014102[APS].
- H. You and Q. M. Zhang:
Phys. Rev. Lett. 79 (1997) 3950[APS].
- N. Takesue, Y. Fujii, and H. You:
Phys. Rev. B 64 (2001) 184112[APS].
- G. Xu, Z. Zhong, H. Hiraka, and G. Shirane:
Phys. Rev. B 70 (2004) 174109[APS].
- D. La-Orauttapong, J. Toulouse, J. L. Robertson, and Z.-G. Ye:
Phys. Rev. B 64 (2001) 212101[APS].
- D. La-Orauttapong, J. Toulouse, Z.-G. Ye, W. Chen, R. Erwin, and J. L. Robertson:
Phys. Rev. B 67 (2003) 134110[APS].
- K. Hirota, Z.-G. Ye, S. Wakimoto, P. M. Gehring, and G. Shirane:
Phys. Rev. B 65 (2002) 104105[APS].
- B. Dkhil, J. M. Kiat, G. Calvarin, G. Baldinozzi, S. B. Vakhrushev, and E. Suard:
Phys. Rev. B 65 (2001) 024104[APS].
- S. B. Vakhrushev, A. A. Naberezhnov, N. M. Okuneva, and B. N. Savenko: Phys. Solid State 37 (1995) 1993.
- J. Hlinka, S. Kamba, J. Petzelt, J. Kulda, C. A. Randall, and S. J. Zhang:
J. Phys.: Condens. Matter 15 (2003) 4249[IoP STACKS].
- S. B. Vakhrushev, A. Ivanov, and J. Kulda: Phys. Chem. Chem. Phys. 7 (2005) 2340.
- G. Xu, G. Shirane, J. R. D. Copley, and P. M. Gehring:
Phys. Rev. B 69 (2004) 064112[APS].
- I.-K. Jeong, T. W. Darling, J. K. Lee, T. Proffen, R. H. Heffner, J. S. Park, K. S. Hong, W. Dmowski, and T. Egami:
Phys. Rev. Lett. 94 (2005) 147602[APS].
- G. Xu, P. M. Gehring, and G. Shirane:
Phys. Rev. B 72 (2005) 214106[APS].
- G. Xu, P. M. Gehring, and G. Shirane:
Phys. Rev. B 74 (2006) 104110[APS].
- P. M. Gehring, K. Ohwada, and G. Shirane:
Phys. Rev. B 70 (2004) 014110[APS].
- G. Xu, Z. Zhong, Y. Bing, Z.-G. Ye, and G. Shirane: Nat. Mater. 5 (2006) 134.
- C. Stock, G. Xu, P. M. Gehring, H. Luo, X. Zhao, H. Cao, J. F. Li, D. Viehland, and G. Shirane:
Phys. Rev. B 76 (2007) 064122[APS].
- G. Xu, J. Wen, C. Stock, and P. M. Gehring: Nat. Mater. 7 (2008) 562.
- C. Stock, H. Luo, D. Viehland, J. F. Li, I. Swainson, R. J. Birgeneau, and G. Shirane:
J. Phys. Soc. Jpn. 74 (2005) 3002[JPSJ].
- C. Stock, R. J. Birgeneau, S. Wakimoto, J. S. Gardner, W. Chen, Z.-G. Ye, and G. Shirane:
Phys. Rev. B 69 (2004) 094104[APS].
- F. Jona and G. Shirane: Ferroelectric Crystals (Dover Publications, New York, 1993).
- Z.-G. Ye, Y. Bing, J. Gao, A. A. Bokov, P. Stephens, B. Noheda, and G. Shirane:
Phys. Rev. B 67 (2003) 104104[APS].
- M. Matsuura, K. Hirota, P. M. Gehring, Z.-G. Ye, W. Chen, and G. Shirane:
Phys. Rev. B 74 (2006) 144107[APS].
- C. Stock, D. Ellis, I. P. Swainson, G. Xu, H. Hiraka, Z. Zhong, H. Luo, X. Zhao, D. Viehland, R. J. Birgeneau, and G. Shirane:
Phys. Rev. B 73 (2006) 064107[APS].
- S. Wakimoto, C. Stock, R. J. Birgeneau, Z.-G. Ye, W. Chen, W. J. L. Buyers, P. M. Gehring, and G. Shirane:
Phys. Rev. B 65 (2002) 172105[APS].
- S. B. Vakhrushev, A. A. Naberezhnov, N. M. Okuneva, and B. N. Savenko: Phys. Solid State 40 (1998) 1728.
- G. Shirane, J. D. Axe, and J. Harada:
Phys. Rev. B 2 (1970) 155[APS].
- P. M. Gehring, S. Wakimoto, Z.-G. Ye, and G. Shirane:
Phys. Rev. Lett. 87 (2001) 277601[APS].
- P. M. Gehring, S.-E. Park, and G. Shirane:
Phys. Rev. Lett. 84 (2000) 5216[APS].
- P. M. Gehring, S.-E. Park, and G. Shirane:
Phys. Rev. B 63 (2001) 224109[APS].
- H. Cao, C. Stock, G. Xu, P. M. Gehring, J. Li, and D. Viehland:
Phys. Rev. B 78 (2008) 104103[APS].
- Z. Wu and R. E. Cohen:
Phys. Rev. Lett. 95 (2005) 037601[APS].
- Z. Kutnjak, J. Petzelt, and R. Blinc:
Nature 441 (2006) 956[CrossRef].
- J. Frantti, Y. Fujioka, and R. M. Nieminen:
J. Phys. Chem. B 111 (2007) 4287[CrossRef].
- M. Budimir, D. Damjanovic, and N. Setter:
Phys. Rev. B 73 (2006) 174106[APS].
- K. Ohwada, K. Hirota, H. Terauchi, T. Fukuda, S. Tsutsui, A. Q. R. Baron, J. Mizuki, H. Ohwa, and N. Yasuda:
Phys. Rev. B 77 (2008) 094136[APS].
- J. Wen, G. Xu, C. Stock, and P. M. Gehring:
Appl. Phys. Lett. 93 (2008) 082901[AIP Scitation].
- Z. Xu, J. Wen, G. Xu, C. Stock, J. S. Gardner, and P. M. Gehring: private communication.
- J. Wen, G. Xu, C. Stock, P. M. Gehring, Z. Zhong, L. A. Boatner, E. L. Venturini, and G. A. Samara:
Phys. Rev. B 78 (2008) 144202[APS].