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SPECIAL TOPICS
Photo-Induced Phase Transitions and their Dynamics
Photo-Induced Phase Transition in an Electron–Lattice Correlated System –Future Role of a Time-Resolved X-ray Measurement for Materials Science–
Shin-ya Koshihara1,2,3 and
Shin-ichi Adachi2,3
1Department of Materials Science and Frontier Collaborative Research Center, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551
2Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801
3Non-equilibrium Dynamics Project, ERATO, Japan Science and Technology Agency, c/o KEK, 1-1 Oho, Tsukuba, Ibaraki 305-0801
(Received September 12, 2005; Accepted October 6, 2005; Published January 10, 2006)
The search for materials that show a phase transition triggered by weak external stimulation of light is an important and attractive target for photonic and materials science. We review experimental evidence indicating that photo-injected local excitation can really trigger an electron–lattice coupled cooperative phenomenon called photo-induced phase transition (PIPT). We discuss the dynamical nature of electron (spin)–lattice-coupled changes in π-conjugated polymer crystals, organic transition metal complexes, and organic A2B charge transfer complexes. We also review the development of ultra-fast X-ray technology in collaboration with work in the fields of quantum electronics and synchrotron radiation, which are essential for the promotion of the future study of PIPT.
©2006 The Physical Society of Japan
URL:
http://jpsj.ipap.jp/link?JPSJ/75/011005/
DOI: 10.1143/JPSJ.75.011005
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